Overcoming kinetic barriers of remote electrochemiluminescence on boron-doped diamond via catalytic coreactant oxidation
At a Glance
Section titled āAt a Glanceā| Metadata | Details |
|---|---|
| Publication Date | 2025-01-01 |
| Journal | Chemical Communications |
| Authors | Alessandro Fracassa, Chiara Mariani, Andrea Fiorani, Yasuaki Einaga, Conor F. Hogan |
| Institutions | Centre National de la Recherche Scientifique, Institute of Condensed Matter Chemistry and Technologies for Energy |
| Citations | 5 |
Abstract
Section titled āAbstractāUsing an Ir( iii )-based redox mediator ([Ir(sppy) 3 ] 3- ) overcomes the traditional kinetic barrier of tri- n -propylamine oxidation on BDD, enhancing the ECL from Ru( ii )-labeled beads by up to 46-fold.