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Atomically-thin single-photon sources for quantum communication

MetadataDetails
Publication Date2023-01-27
Journalnpj 2D Materials and Applications
AuthorsTimm Gao, Martin von Helversen, C. AntĂłn, Christian Schneider, Tobias Heindel
InstitutionsCarl von Ossietzky UniversitÀt Oldenburg, Technische UniversitÀt Berlin
Citations72
AnalysisFull AI Review Included

Technical Documentation & Analysis: Atomically-Thin Single-Photon Sources for Quantum Communication

Section titled “Technical Documentation & Analysis: Atomically-Thin Single-Photon Sources for Quantum Communication”

Reference: Gao et al., npj 2D Materials and Applications (2023)7:4.

This research demonstrates the successful implementation of a strain-engineered WSe₂ monolayer as a deterministic single-photon source (SPS) for Quantum Key Distribution (QKD) using the BB84 protocol.

  • Application Validation: Pioneers the practical suitability of atomically-thin Transition Metal Dichalcogenides (TMDCs) for robust quantum communication systems.
  • High Purity: Achieved exceptional single-photon purity, with a post-processed antibunching value $g^{(2)}(0)$ down to 0.034 ± 0.002, competitive with leading solid-state emitters.
  • Performance Metrics: Demonstrated click rates up to 66.95 kHz at a 5.0 MHz clock rate, resulting in a mean photon number per pulse ($\mu$) of up to 0.024 in the quantum channel.
  • Extended Range: Optimization via 2D temporal filtering extended the maximally tolerable transmission loss to 22.59 dB, corresponding to a free-space communication distance extension of 43.9 km.
  • Benchmarking Opportunity: The study explicitly benchmarks the WSe₂ performance against established solid-state quantum emitters, including color centers in diamond and semiconductor quantum dots, highlighting the critical role of high-purity diamond materials supplied by 6CCVD in this competitive field.
  • Future Direction: The work paves the way for highly integrated, low-cost quantum light sources, though further improvements in extraction efficiency (e.g., via microcavities) are required to match the performance potential of optimized diamond-based systems.

The following table summarizes the key performance metrics and physical parameters extracted from the experimental results.

ParameterValueUnitContext
Emitter MaterialWSe₂ MonolayerN/AStrain-engineered TMDC
Operation Wavelength ($\lambda$)807.3nmFirst telecom window
Excitation Wavelength660nmPulsed diode laser
Optimal Clock Rate5.0MHzUsed for QKD experiments
Saturation Pump Power ($P_{sat}$)52.5”WPower at which click rate saturates
Maximum Click Rate (Pulsed)66.95 ± 1.07kHzTotal signal from four channels
Single-Photon Purity ($g^{(2)}(0)$)0.17N/AUnfiltered, 5.0 MHz clock rate
Minimum $g^{(2)}(0)$0.034 ± 0.002N/APost-processed (24 ns acceptance window)
Mean Photon Number ($\mu$)Up to 0.024N/AInto the quantum channel
QBER (Lower Bound)0.52%Set by receiver optics
Max Tolerable Loss (Optimized)22.59dBAchieved via 2D temporal filtering
Substrate StackSapphire / 10 nm Cr / 200 nm AgN/ANano-structured metallic surface

The experiment utilized a proof-of-concept QKD testbed emulating the BB84 protocol, focusing on the characterization of the WSe₂ single-photon source (SPS).

  1. TMDC Device Preparation: WSe₂ monolayer sheets were mechanically exfoliated and transferred onto a nano-structured metallic surface (Sapphire substrate capped with 10 nm Chromium and 200 nm Silver) to induce strain centers for localized quantum emitters.
  2. Source Operation (Alice): The WSe₂ device was mounted in a closed-cycle cryocooler (4.2 K) and excited using a pulsed diode laser (660 nm) with a variable repetition rate (optimized at 5.0 MHz).
  3. Collection and Filtering: Emission was collected via an aspheric lens (NA = 0.77), spectrally filtered using two long-pass (LP) filters (750 nm and 800 nm cut-ons), and coupled into a single-mode (SM) optical fiber.
  4. Polarization Encoding: Single photons were prepared in four BB84 polarization states (H, V, D, A) using a fiber polarization controller and a Glan-Thompson prism (static preparation for proof-of-concept).
  5. QKD Receiver (Bob): The receiver comprised a four-state polarization decoder with passive basis choice (50:50 beamsplitter cube and polarizing beamsplitters) and utilized four silicon-based single-photon counting modules (SPCMs) with 80% efficiency at 810 nm.
  6. Performance Optimization: The secret key rate was optimized by applying 2D temporal filtering (varying acceptance time window $\Delta t$ and center $t_c$) to maximize the signal-to-noise ratio and reduce the contribution of detector dark counts and background noise.

The research highlights the intense competition in deterministic quantum light sources, explicitly comparing TMDCs to diamond color centers. 6CCVD provides the foundational material technology necessary to advance and surpass the performance demonstrated by TMDC systems, particularly in high-stability, high-temperature quantum applications.

While this paper focuses on WSe₂, the highest performing solid-state quantum emitters for QKD, such as Nitrogen-Vacancy (NV) and Silicon-Vacancy (SiV) centers, rely on high-purity Single Crystal Diamond (SCD).

6CCVD MaterialApplication RelevanceKey Advantage over TMDCs
Optical Grade SCDHosting NV, SiV, GeV, and SnV color centers for deterministic SPS and quantum memory.Superior thermal conductivity, high stability, and potential for room-temperature operation (NV centers).
High-Purity SCDSubstrates for epitaxial growth or ion implantation of quantum defects.Extremely low defect density, crucial for achieving high photon indistinguishability and coherence times.
Boron-Doped Diamond (BDD)High-efficiency, radiation-hard single-photon detectors and electrodes for integrated quantum circuits.Excellent electrical properties and chemical inertness for device integration.

Customization Potential for Integrated Quantum Devices

Section titled “Customization Potential for Integrated Quantum Devices”

The complexity of the WSe₂ device (requiring a specialized Cr/Ag metallic surface and cryogenic operation) underscores the need for highly customized material solutions. 6CCVD is uniquely positioned to supply the necessary diamond components for next-generation quantum devices.

Requirement in Research6CCVD Custom CapabilityBenefit to Quantum Engineers
Substrate IntegrationCustom SCD/PCD plates and wafers up to 125mm in diameter. Substrate thickness up to 10mm.Enables large-scale integration of diamond quantum chips and compatibility with standard semiconductor processing.
Surface QualitySCD polishing to Ra < 1 nm; PCD polishing to Ra < 5 nm.Essential for high-Q microcavity integration (as suggested for TMDC improvement) and minimizing scattering losses in photonic circuits.
Metalization LayersInternal capability for custom metalization (Au, Pt, Pd, Ti, W, Cu).Allows for direct fabrication of electrical contacts, microwave waveguides, and strain-engineering layers on diamond substrates.
Unique DimensionsCustom laser cutting and shaping services.Provides precise geometries required for solid-immersion lenses (SILs) and photonic crystal structures necessary for efficient photon extraction.

The optimization routines discussed in the paper (temporal filtering, material selection, and integration) require deep expertise in solid-state physics and quantum optics.

6CCVD’s in-house PhD engineering team specializes in the material science of diamond quantum systems. We offer consultation services to assist researchers and engineers in selecting the optimal diamond material (SCD purity, BDD doping level, surface termination) for similar deterministic single-photon source and QKD projects.

For custom specifications or material consultation, visit 6ccvd.com or contact our engineering team directly.

View Original Abstract

Abstract To date, quantum communication widely relies on attenuated lasers for secret key generation. In future quantum networks, fundamental limitations resulting from their probabilistic photon distribution must be overcome by using deterministic quantum light sources. Confined excitons in monolayers of transition metal dichalcogenides (TMDCs) constitute an emerging type of emitter for quantum light generation. These atomically thin solid-state sources show appealing prospects for large-scale and low-cost device integration, meeting the demands of quantum information technologies. Here, we pioneer the practical suitability of TMDC devices in quantum communication. We employ a WSe 2 monolayer single-photon source to emulate the BB84 protocol in a quantum key distribution (QKD) setup and achieve click rates of up to 66.95 kHz and antibunching values down to 0.034—a performance competitive with QKD experiments using semiconductor quantum dots or color centers in diamond. Our work opens the route towards wider applications of quantum information technologies using TMDC single-photon sources.