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Efficient and robust signal sensing by sequences of adiabatic chirped pulses

MetadataDetails
Publication Date2020-08-07
JournalPhysical Review Research
AuthorsGenko T. Genov, Yachel Ben-Shalom, Fedor Jelezko, Alex Retzker, Nir Bar‐Gill
InstitutionsCenter for Integrated Quantum Science and Technology, Hebrew University of Jerusalem
Citations17
AnalysisFull AI Review Included

Technical Documentation & Analysis: Robust Quantum Sensing via RAP-XY8 in MPCVD Diamond

Section titled “Technical Documentation & Analysis: Robust Quantum Sensing via RAP-XY8 in MPCVD Diamond”

This document analyzes the research paper, “Efficient and robust signal sensing by sequences of adiabatic chirped pulses,” focusing on the material requirements and experimental achievements related to Nitrogen-Vacancy (NV) centers in diamond. It highlights how 6CCVD’s advanced MPCVD diamond materials and customization capabilities can support and extend this critical quantum sensing research.


The research successfully demonstrates a highly robust and efficient method for AC quantum sensing using phased Rapid Adiabatic Passage (RAP) pulse sequences (RAP-XY8) in ensemble NV centers in diamond.

  • Core Achievement: RAP-XY8 sequences significantly enhance the coherence time ($T_2$) and robustness of AC magnetometry compared to standard XY8 protocols.
  • Performance Metric: Achieved a maximum $T_2$ of 1943 ± 231 ”s, demonstrating superior performance in systems with large inhomogeneous broadening ($2\pi \times 2.1$ MHz).
  • Robustness: The RAP protocol proved robust against both driving field amplitude noise and low Rabi frequency conditions, where standard XY8 performance degraded significantly (up to 45% drop in $T_2$).
  • Mechanism: Adiabatic chirped pulses act as a double filter for dynamical decoupling (DD), rectifying the signal and partially removing frequency noise.
  • Sensitivity: Direct measurements showed a ~30% improvement in magnetic sensitivity ($\eta$) for RAP sequences over regular XY8 under optimized conditions.
  • Material Requirement: The experiment relies on high-quality diamond substrates suitable for NV creation and microwave integration, confirming diamond’s role as the premier platform for robust quantum sensing.

The following hard data points were extracted from the experimental results and simulations, highlighting the performance achieved using the RAP-XY8 protocol in NV diamond.

ParameterValueUnitContext
SCD Coherence Time (RAP-XY8, Optimized)1943 ± 231”sHigh Rabi experiment
SCD Coherence Time (Standard XY8, Optimized)1811 ± 184”sHigh Rabi experiment
SCD Coherence Time (RAP-XY8, Low Rabi)1850 ± 389”sRobustness test, $\Omega_0 = 2\pi \times 1.7$ MHz
Inhomogeneous Broadening (FWHM)$2\pi \times (2.1 \pm 0.1)$MHzExperimental sample characteristic
Peak Rabi Frequency ($\Omega_0$)$2\pi \times 5$MHzHigh Rabi experiment
Target Chirp Range (R)$2\pi \times 40$MHzOptimized for High Rabi
Pulse Duration ($T_{pulse}$)11.4”sHigh Rabi experiment
Minimum Sensitivity ($\eta_{min,RAP}$)22 ± 4nT·Hz-1/2High Rabi with noise
Sensitivity Improvement (RAP vs XY8)~30%Direct measurement
NV Density~10ppbStandard-grade diamond sample
Static Bias Field332GaussExperimental setup

The experimental demonstration utilized advanced microwave control techniques on a diamond substrate hosting NV ensembles.

  1. Material Selection: A standard-grade diamond sample (Element Six) with an NV density of approximately 10 ppb was used as the sensing platform.
  2. Optical Initialization: NV centers were initialized to the $|0\rangle$ spin state via optical pumping using a 532 nm green laser source.
  3. Magnetic Environment: Experiments were conducted in a home-built confocal fluorescence microscope under a static magnetic bias field of 332 Gauss.
  4. Microwave Control Generation: Modulated microwave control fields, necessary for generating the complex chirped adiabatic pulses, were created using a high-speed Arbitrary Waveform Generator (AWG - Tektronix AWG70002A, 16 Gs).
  5. Pulse Sequence Implementation: The RAP-XY8 sequence was implemented using phased, adiabatic, chirped pulses based on the Allen-Eberly model, optimized experimentally for characteristic time ($T$) and chirp range ($R$).
  6. AC Field Sensing: An external AC magnetic signal was applied using a home-built coil driven by a function generator (Rigol 5252).
  7. Readout: Spin-dependent fluorescence (650-800 nm) was collected to measure the population transfer and determine coherence time ($T_2$) and magnetic sensitivity ($\eta$).

This research validates the use of advanced pulse sequences to overcome material limitations (inhomogeneous broadening, noise) inherent in standard diamond samples. 6CCVD provides the high-specification MPCVD diamond materials and customization services necessary to replicate, optimize, and scale this robust quantum sensing technology.

Research Requirement/Challenge6CCVD Solution & CapabilityTechnical Advantage for Replication/Extension
High Coherence Time ($T_2$)High Purity Single Crystal Diamond (SCD)Our SCD features ultra-low nitrogen (< 1 ppb) and controlled NV creation, minimizing the spin bath noise that limits $T_2$. This enables coherence times significantly longer than the 1.94 ms reported, crucial for maximizing sensing precision ($\eta \propto 1/\sqrt{T_2}$).
Large Area Ensemble SensingPolycrystalline Diamond (PCD) WafersWe offer custom PCD plates up to 125mm diameter. This is ideal for scaling up ensemble NV magnetometry and integrating large-area sensors into practical devices.
Robustness to Inhomogeneous BroadeningCustom NV Density Control6CCVD provides precise control over NV creation (via implantation or in-situ growth) to optimize NV density, allowing researchers to balance signal strength against broadening effects for specific applications.
Integrated Microwave ControlCustom Metalization ServicesWe offer internal metalization capabilities (Au, Pt, Pd, Ti, W, Cu). This is essential for fabricating high-fidelity on-chip microwave transmission lines (e.g., coplanar waveguides) directly onto the diamond surface, improving driving field homogeneity.
Optical Readout EfficiencyUltra-Low Roughness PolishingSCD polishing to Ra < 1 nm and inch-size PCD polishing to Ra < 5 nm ensures optimal surface quality for efficient optical coupling (532 nm excitation) and fluorescence collection (650-800 nm).
Substrate DimensionsCustom Dimensions and ThicknessesWe supply SCD wafers from 0.1 ”m to 500 ”m thick, and substrates up to 10 mm thick, accommodating specific requirements for high-power MW delivery or thermal management.

6CCVD’s in-house PhD team specializes in MPCVD diamond growth and post-processing for quantum applications. We offer consultation services to assist researchers in selecting the optimal material specifications (e.g., SCD vs. PCD, specific NV doping levels, and surface preparation) required to replicate or extend this robust RAP-XY8 quantum sensing project.

For custom specifications or material consultation, visit 6ccvd.com or contact our engineering team directly.

View Original Abstract

We propose a scheme for sensing of an oscillating field in systems with large inhomogeneous broadening and driving field variation by applying sequences of phased, adiabatic, chirped pulses. These act as a double filter for dynamical decoupling, where the adiabatic changes of the mixing angle during the pulses rectify the signal and partially remove frequency noise. The sudden changes between the pulses act as instantaneous π pulses in the adiabatic basis for additional noise suppression. We also use the pulses’ phases to correct for other errors, e.g., due to nonadiabatic couplings. Our technique improves significantly the coherence time in comparison to standard XY8 dynamical decoupling in realistic simulations in NV centers with large inhomogeneous broadening. Beyond the theoretical proposal, we also present proof-of-principle experimental results for quantum sensing of an oscillating field in NV centers in diamond, demonstrating superior performance compared to the standard technique.