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Quantum Frequency Conversion of Single Photons from a Nitrogen-Vacancy Center in Diamond to Telecommunication Wavelengths

MetadataDetails
Publication Date2018-06-19
JournalPhysical Review Applied
AuthorsAnaïs Dréau, Anna Tcheborateva, Aboubakr El Mahdaoui, Cristian Bonato, Ronald Hanson
InstitutionsCentre National de la Recherche Scientifique, QuTech
Citations120
AnalysisFull AI Review Included

Technical Documentation & Analysis: Quantum Frequency Conversion in Diamond NV Centers

Section titled “Technical Documentation & Analysis: Quantum Frequency Conversion in Diamond NV Centers”

This analysis addresses the critical material requirements and engineering solutions needed to replicate and advance the findings presented in “Quantum frequency conversion to telecom of single photons from a nitrogen-vacancy center in diamond.”


This paper successfully demonstrates the integration of diamond-based quantum emitters into existing fiber optic networks via Quantum Frequency Conversion (QFC). The core achievements and technological significance are summarized below:

  • Quantum Interface Demonstrated: Successful frequency down-conversion of spin-selective single photons emitted by a Nitrogen-Vacancy (NV) center in diamond.
  • Wavelength Transduction: Photons at 637 nm (Visible/Red, corresponding to the coherent NV ZPL) were converted to 1588 nm (Telecom L-band), drastically reducing fiber transmission loss (from ≈ 8 dB/km to < 0.2 dB/km).
  • High Efficiency & Fidelity: Achieved a total conversion efficiency of $\approx$ 17% and confirmed the preservation of the single-photon statistics via anti-bunching measurements (g(2)(0) = 0.32 after conversion).
  • Signal Quality: Demonstrated a Signal-to-Noise Ratio (SNR) of $\approx$ 7, limited by pump-induced noise (Spontaneous Parametric Down-Conversion, SPDC) in the PPLN waveguide.
  • Paving the Way for Networks: This result represents a key technological step toward developing long-range entanglement-based quantum networks using robust solid-state NV qubits housed in high-purity Single Crystal Diamond (SCD).

ParameterValueUnitContext / Function
Input Photon (Signal)637nmNV Center Zero-Phonon-Line (ZPL)
Output Photon (Idler)1588nmTelecom L-Band (Target Wavelength)
Pump Laser1064nmContinuous-Wave (CW) DFG Source
Max Pump Power (Optimal)$\approx$ 110mWInput power maximizing detection probability $p_{c,tel}$
Total Conversion Efficiency ($\eta_{c}$)17%Overall system efficiency (diamond to detector)
Internal PPLN Conversion $\eta_{int}$$\approx$ 65%Estimated efficiency inside the PPLN crystal
Signal-to-Noise Ratio (SNR)$\approx$ 7-Achieved at optimal conversion settings
Converted Photon Statistics (g(2)(0))0.32 $\pm$ 0.08-Shows preservation of anti-bunching, proving single-photon nature
NV Excited State Lifetime ($\tau$@637nm)12.9 $\pm$ 1.0nsBaseline for spin-selective transition
Converted Photon Lifetime ($\tau$@1588nm)12.6 $\pm$ 1.2nsConfirms conversion preserves temporal characteristics
PPLN Waveguide Dimensions8 x 8 x 48”m x ”m x mmCore element for Difference Frequency Generation (DFG)

The success of the QFC experiment relies on precise control over the NV photon source parameters and highly efficient nonlinear optical conversion techniques:

  1. High-Purity Diamond Source: Utilized a single NV center embedded in a diamond host. The NV center was addressed using a spin-selective optical transition.
  2. Pulsed Resonant Excitation: The NV center was resonantly driven by a 2-ns optical $\pi$-pulse, ensuring conditional single-photon emission (on the spin state).
  3. Photon Extraction & Coupling: NV photons were extracted from the diamond, coupled into a Polarization-Maintaining (PM) fiber, and directed to the down-conversion stage.
  4. Difference Frequency Generation (DFG): Implemented using a strong 1064 nm CW pump laser and the 637 nm NV photon, mixing them in a Zn-doped Type-0 Periodically-Poled Lithium Niobate (PPLN) waveguide.
  5. Quasi-Phase Matching (QPM): Achieved by careful thermal tuning of the PPLN crystal temperature to optimize the DFG process.
  6. Multi-Stage Spectral Noise Filtering: To overcome the low input photon rate and high pump noise (SPDC), a rigorous filtering chain was employed:
    • Dispersive Prism
    • Long-pass Filter (Semrock BLP01-1550R-25)
    • Narrow-band Fiber Bragg Grating (FBG) filter (4 pm / 500 MHz bandwidth).
  7. Time-Correlated Detection: Used a Superconducting Single Photon Detector (SSPD) synchronized to the NV center excitation pulse, enabling temporal filtering to maximize the SNR.

This research highlights the absolute necessity of high-quality, ultra-pure Single Crystal Diamond (SCD) for scaling quantum networks. 6CCVD provides the specialized MPCVD diamond material and engineering services required to replicate this work and advance subsequent generations of solid-state quantum emitters.

To achieve the long coherence times and minimal spectral diffusion required for high-fidelity NV center performance, researchers must start with optimal diamond material.

Material Requirement (Paper Implied)6CCVD Recommended SolutionKey Benefit for Application
Ultra-high Purity SubstrateOptical Grade Single Crystal Diamond (SCD)Minimal background nitrogen and defect density, crucial for long NV spin coherence ($\tau$ up to 1 second demonstrated elsewhere).
Custom Thickness ControlSCD Films: 0.1 ”m - 500 ”mAllows precise integration of the NV layer relative to the surface for optimal coupling to external structures (e.g., PPLN waveguides or on-chip devices).
Controlled DopingNitrogen-Controlled SCD GrowthTargeted incorporation of nitrogen atoms to maximize the density and quality of isolated NV centers, enhancing ZPL count rates.

The paper noted that future SNR improvements rely on “increased collection efficiency” and “Purcell enhancement” via structures like microcavities or parabolic reflectors. 6CCVD specializes in the engineering required for these structures.

  • Precision Fabrication: We offer Custom Laser Micromachining to etch precise patterns, trenches, or mesas onto the SCD substrate, enabling the fabrication of integrated optical components like solid-immersion lenses or parabolic reflectors used for enhancing NV photon collection efficiency (addressing a key bottleneck mentioned in the paper).
  • Surface Preparation: The high coupling efficiency (estimated $\approx$ 90% into the PPLN waveguide) necessitates near-perfect optical interfaces. 6CCVD guarantees ultra-low surface roughness: SCD substrates are polished to Ra < 1 nm, significantly minimizing scattering losses.
  • Metalization Services: While this study focused on DFG, other quantum components (e.g., microwave control structures, on-chip heaters) may require custom electrodes. 6CCVD provides in-house metalization services (Au, Pt, Pd, Ti, W, Cu) tailored for demanding cryogenic or high-power applications.

Our role as technical partners extends beyond material supply. The challenges highlighted in the paper—including low ZPL emission rate and noise filtering—require specialized knowledge of MPCVD diamond processing.

  • Application Expertise: 6CCVD’s in-house PhD team provides consultative support on material selection for Solid-State Quantum Emitter projects, including NV and SiV centers. We assist clients in optimizing diamond growth recipes specifically to maximize the ZPL extraction efficiency and minimize spectral diffusion.
  • Global Supply Chain: We ensure reliable delivery of custom diamond plates and wafers (up to 125 mm PCD) globally, with flexible DDU (default) and DDP shipping terms.

For custom specifications or material consultation, visit 6ccvd.com or contact our engineering team directly.

View Original Abstract

We report on the conversion to telecom wavelength of single photons emitted\nby a nitrogen-vacancy (NV) defect in diamond. By means of difference frequency\ngeneration, we convert spin-selective photons at 637 nm, associated with the\ncoherent NV zero-phonon-line, to the target wavelength of 1588 nm in the\nL-telecom band. The successful conversion is evidenced by time-resolved\ndetection revealing a telecom photon lifetime identical to that of the original\n637 nm photon. Furthermore, we show by second-order correlation measurements\nthat the single-photon statistics are preserved. The overall efficiency of this\none-step conversion reaches 17\% in our current setup, along with a\nsignal-to-noise ratio of $\approx$7 despite the low probability $(< 10^{-3})$\nof an incident 637 nm photon. This result shows the potential for efficient\ntelecom photon - NV center interfaces and marks an important step towards\nfuture long-range entanglement-based quantum networks.\n