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Measurement-device-independent quantum key distribution with nitrogen vacancy centers in diamond

MetadataDetails
Publication Date2017-02-27
JournalPhysical review. A/Physical review, A
AuthorsNicolĂČ Lo Piparo, Mohsen Razavi, William J. Munro
InstitutionsNational Institute of Informatics, University of Leeds
Citations38
AnalysisFull AI Review Included

Technical Analysis & Product Opportunity: NV Centers for Quantum Communication

Section titled “Technical Analysis & Product Opportunity: NV Centers for Quantum Communication”

6CCVD provides the foundational MPCVD diamond materials necessary to realize next-generation Memory-Assisted Measurement-Device-Independent Quantum Key Distribution (MA-MDI-QKD) systems. This analysis confirms that the successful implementation of long-distance quantum communication based on Nitrogen Vacancy (NV) centers critically depends on high-quality, engineered Single Crystal Diamond (SCD) platforms.


  • Core Finding: Non-cavity NV centers in diamond are insufficient to outperform existing no-Quantum Memory (no-QM) QKD systems, even under optimistic assumptions.
  • Critical Requirement: Outperforming conventional QKD schemes requires cavity-enhanced NV centers (NV centers embedded in small-volume optical microcavities) to achieve efficient spin-photon coupling and high repetition rates.
  • Performance Advantage: Proposed cavity-enhanced schemes, utilizing electron spin coherence times ($T_2$) of 100 ms, are anticipated to outperform no-QM MDI-QKD by nearly an order of magnitude at distances around 400 km.
  • Feasibility: The required strong coupling regime is characterized by a low cooperativity value ($C \ge 1$), which is within the reach of current fabrication efforts using high-purity SCD.
  • Technical Challenge: Successful implementation relies on mastering three key operations using a double-encoding module: Initialization, Memory Loading (entanglement), and Readout/Final Bell-State Measurement (BSM).
  • Material Necessity: MPCVD Single Crystal Diamond (SCD) is essential for fabricating the integrated microcavities necessary for the required strong-coupling regime.

The following parameters, extracted from the analysis of the proposed cavity-enhanced NV center scheme (6CCVD’s target market), define the required operational scope for competitive MA-MDI-QKD.

ParameterValueUnitContext
Required Cooperativity (C)$\ge 1$UnitlessMinimum threshold for beating no-QM systems. $C=50$ offers significant rate advantage.
Electron Spin Coherence ($T_2$)100 msmsTypical $T_2$ achieving performance advantage over 400 km.
Nuclear Spin Coherence ($T_2$)10 ssPotential maximum coherence, enabling advantages over longer distances (> 500 km).
MA-MDI-QKD Repetition Rate ($R_s$)40 MHzHzRequired for the cavity-based NV center scheme.
Photon Interaction Time ($\tau_{\text{int}}$)10 nsnsEstimated time for double-encoding procedure.
Initialization Time ($\tau_{\text{init}}$)14 nsnsTime required to prepare the NV center state.
Deadtime ($\tau_{\text{dead}}$) (Estimate)500 nsnsTime lost due to overstaying in metastable states.
Entangling/Loading Efficiency ($\eta$)0.9UnitlessTarget efficiency for the double-encoding module.
Operation Distance Advantage300 to 500kmRange where cavity-enhanced NV centers outperform conventional QKD.
Required Temperature4 to 8KNecessary for state-dependent optical coupling and stability.

The core of the successful MA-MDI-QKD protocol relies on cavity-enhanced NV centers operating as conditional reflection modules within a sophisticated double-encoding scheme (Figure 4).

  1. Material Preparation:

    • High-purity Single Crystal Diamond (SCD) substrate is used to host NV centers.
    • NV centers are embedded into small-volume, one-sided optical microcavities.
    • Cavity resonance frequency ($\omega_c$) is tuned to match the $|s_0\rangle \to |E_x\rangle$ transition of the NV center.
  2. Conditional Reflection Principle:

    • The internal spin state of the NV center (e.g., $|s_0\rangle$ versus $|s_{+1}\rangle$) dictates the effective reflectivity ($A_r$) of the embedding cavity.
    • If the NV is in $|s_0\rangle$, the incoming photon is reflected as if by a mirror ($A_r \sim 1$).
    • If the NV is in $|s_{+1}\rangle$, the photon is reflected but acquires a different phase shift.
  3. Double-Encoding Module (Initialization, Loading, Readout):

    • Initialization ($\tau_{\text{init}} \approx 14$ ns): The NV center is prepared in a superposition state $| \Psi_{\text{in}} \rangle = (|s_0\rangle + |s_{+1}\rangle)/\sqrt{2}$. This uses the conditional reflection to project the spin state based on the output photon polarization.
    • Memory Loading (Entanglement): A polarized single photon interacts with the initialized NV center via the cavity. The state results in entanglement between the photon polarization ($|H\rangle, |V\rangle$) and the electron spin state ($|s_0\rangle, |s_{+1}\rangle$), with a target efficiency $\eta \approx 0.9$.
    • Readout ($\tau_{\text{readout}} \approx 25$ ns): The memory state is transferred back to a photonic state using the same double-encoding module, followed by an X-basis measurement on the NV center spin to perform the final Bell-State Measurement (BSM).

This research validates the market need for bespoke, high-purity SCD engineered for quantum applications. 6CCVD is uniquely positioned to supply the foundational materials and custom fabrication services required to transition this theoretical advantage into practical hardware.

To replicate and extend the successful cavity-enhanced NV center MA-MDI-QKD scheme, researchers require material with ultra-low native defects and supreme surface quality necessary for cavity integration.

6CCVD Material RecommendationSpecification AlignmentTarget Application
Optical Grade Single Crystal Diamond (SCD)Ultra-low Nitrogen content, minimal strain. Essential for stable NV center formation and long electron spin coherence times ($T_2$).Host material for high-fidelity quantum memories.
Thin SCD Wafers (0.1”m - 500”m)Required for integration into various microcavity designs (e.g., photonic crystal cavities, ring resonators) that demand precise layer thickness for optical coupling.Cavity fabrication feedstock.
High-Purity SCD Substrates (up to 10mm thickness)Provides robust support and optimal thermal environment (4-8 K operation).Thermal and structural support for device integration.

The experimental realization of cavity-enhanced NV centers necessitates nanometer-scale precision in geometry and sophisticated interfacing. 6CCVD offers essential customization services:

  • Precision Polishing for Microcavities: Achieving the strong coupling regime requires minimizing scattering and maximizing reflection/transmission control. 6CCVD guarantees Ra < 1nm polishing on SCD, crucial for forming high-Q microcavity mirrors or surfaces used in conditional reflection schemes.
  • Custom Dimensions and Etching Compatibility: We offer plates/wafers up to 125mm (PCD) and custom-cut SCD pieces. Our materials are grown via MPCVD, ensuring superior homogeneity vital for reliable microfabrication processes (e.g., plasma etching for photonic crystal structures).
  • Metallization Layers: Although the core NV physics is optical, interfacing the device requires electrical control. We offer in-house metalization services (Au, Pt, Pd, Ti, W, Cu) for creating control gates, electrodes, and on-chip interconnects necessary for initialization and readout pulse sequences ($\tau_{\text{init}} \approx 14$ ns, $\tau_{\text{readout}} \approx 25$ ns).
  • Laser Cutting Services: For developing customized quantum chips or test platforms, 6CCVD provides precision laser cutting to create unique device footprints from thick substrates or thin SCD layers.

The transition from theoretical modeling (which achieved $C \ge 1$) to physical fabrication is complex. 6CCVD’s in-house PhD material science and technical engineering team is available to assist researchers and engineers with:

  1. Optimizing SCD Growth: Tailoring growth parameters to minimize defects relevant to $T_2$ decoherence and maximize yield of isolated, stable NV centers.
  2. Material Integration Consultancy: Advising on material dimensions, crystal orientation, and surface preparation to ensure maximum compatibility with advanced lithography and cavity fabrication techniques (e.g., ensuring surfaces are ready for E-beam lithography or focused ion beam etching).
  3. Prototyping Needs: Supplying rapid turnaround on custom dimensions and metalized SCD plates for accelerated MA-MDI-QKD prototyping projects.

For custom specifications or material consultation, visit 6ccvd.com or contact our engineering team directly.

View Original Abstract

Memory-assisted measurement-device-independent quantum key distribution (MA-MDI-QKD) has recently been proposed as a possible intermediate step towards the realization of quantum repeaters. Despite its relaxing some of the requirements on quantum memories, the choice of memory in relation to the layout of the setup and the protocol has a stark effect on our ability to beat existing no-memory systems. Here, we investigate the suitability of nitrogen vacancy (NV) centers, as quantum memories, in MA-MDI-QKD. We particularly show that moderate cavity enhancement is required for NV centers if we want to outperform no-memory QKD systems. Using system parameters mostly achievable by today’s state of the art, we then anticipate some total key rate advantage in the distance range between 300 and 500 km for cavity-enhanced NV centers. Our analysis accounts for major sources of error including the dark current, the channel loss, and the decoherence of the quantum memories.