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Hybrid Quantum Device with Nitrogen-Vacancy Centers in Diamond Coupled to Carbon Nanotubes

MetadataDetails
Publication Date2016-06-30
JournalPhysical Review Letters
AuthorsFuli Li, Ze-Liang Xiang, Peter Rabl, Franco Nori
InstitutionsUniversity of Michigan, RIKEN Center for Emergent Matter Science
Citations181
AnalysisFull AI Review Included

Technical Documentation and Analysis: Hybrid NV-Nanotube Quantum Devices

Section titled “Technical Documentation and Analysis: Hybrid NV-Nanotube Quantum Devices”

This research proposes a scalable spin-nanomechanical hybrid quantum device utilizing Nitrogen-Vacancy (NV) centers in diamond coupled via a suspended, current-carrying carbon nanotube (CNT). This setup addresses key challenges in quantum engineering, achieving strong, tunable coupling necessary for quantum information processing (QIP) and advanced sensing.

  • Core Achievement: Demonstration of strong, intrinsic magnetomechanical coupling between a single NV spin and the vibrational mode of a CNT.
  • Coupling Strength: Achieved coupling strength (g/2π) up to 100 kHz, exceeding extrinsic coupling methods and rivaling superconducting circuits.
  • Mechanism: Coupling is driven by the localized magnetic field gradient generated by a DC current (I ~ 60 ”A) flowing through the vibrating nanotube.
  • Material Requirements: Success hinges on using ultrapure Single Crystal Diamond (SCD) to ensure long electronic spin coherence times (T2 ~ 1 ms) at cryogenic temperatures (T ~ 10 mK).
  • Applications: The inherent scalability and strong coupling facilitate complex QIP tasks, including phonon-mediated quantum state transfer (SWAP gates) and the development of novel nanoscale sensors (e.g., pressure, magnetic fields).
  • Analogy: The hybrid system effectively mimics standard cavity Quantum Electrodynamics (QED), allowing dynamic tuning of the interaction type (Jaynes-Cummings or Anti-Jaynes-Cummings) via external microwave control.

The following parameters, extracted from the analysis and required for achieving the strong coupling regime, define the material and operational constraints of the device.

ParameterValueUnitContext
NV Center Coherence Time (T2)~1msRequired for strong coupling, achieved in ultrapure diamond
Nanotube Quality Factor (Q)≄ 105-Mechanical resonator Q-factor (minimum requirement)
Nanotube Fundamental Frequency (ωnt/2π)2MHzMechanical vibration mode
NV Center Implantation Depth5 - 10nmCritical distance from diamond surface
Nanotube-NV Separation (d)10 to 30nmTunable distance for adjusting coupling strength
DC Current (I)~60”ACurrent required to generate localized magnetic field
Maximum Coupling Strength (g/2π)100kHzAchieved at closest separation (d ~ 10 nm)
Operating Temperature (T)~10mKRequired to limit thermal phonon number (nth ~ 100)
NV Center Zero-Field Splitting (D/2π)2.87GHzIntrinsic spin property

The experiment relies on advanced MPCVD diamond fabrication combined with high-precision nanofabrication and cryogenic control.

  1. Diamond Material Preparation: Use ultrapure Single Crystal Diamond (SCD) substrates or high-purity diamond nanocrystals (size < 10 nm) to minimize spin decoherence (T2).
  2. NV Center Engineering: Implant or grow NV centers precisely 5-10 nm below the SCD surface, or host single NV defects within synthesized nanodiamonds.
  3. Nanotube Fabrication and Suspension: Fabricate and suspend a high-Q carbon nanotube resonator (L ~ 2 ”m) across gate electrodes above the diamond sample.
  4. Electrostatic Tuning: Utilize AC and DC voltages applied to gate electrodes to electrostatically actuate the nanotube, enabling fine-tuning of the separation distance ($d$) between the CNT and the NV center.
  5. Magnetic Gradient Generation: Flow a high DC current (I ~ 60 ”A) through the CNT to create a strong, localized magnetic field gradient ($\delta B_{nt}/\delta y$) essential for the magnetomechanical coupling.
  6. Qubit Readout and Control: Employ external microwave fields (via antennas) for coherent spin manipulation (Rabi oscillations) and a confocal microscope setup for optical excitation and photoluminescence readout of the NV spin state.
  7. Cryogenic Operation: Validate the strong coupling regime by operating the hybrid device in a dilution refrigerator at milli-Kelvin temperatures (T ~ 10 mK).

The successful replication and extension of this groundbreaking NV-nanotube quantum research require diamond materials with exceptional purity, surface quality, and precise form factors. 6CCVD is uniquely positioned to supply the advanced MPCVD diamond solutions needed for cryogenic quantum experiments.

To achieve the long spin coherence times (T2 ~ 1 ms) necessary for operating the quantum gates, the highest material purity is paramount.

  • Optical Grade Single Crystal Diamond (SCD): This material is critical for minimizing electronic spin decay rates ($\gamma_s$). 6CCVD supplies isotopically enriched or highly purified SCD substrates, essential for quantum applications requiring T2 maximization.
  • Thin Film SCD: The requirement for NV centers 5-10 nm below the surface necessitates high-quality, ultra-thin diamond films. 6CCVD provides custom SCD thickness control from 0.1 ”m up to 500 ”m, ensuring substrates are compatible with near-surface NV integration techniques.
  • Nanoscale Diamond Precursors: For the nanodiamond setup (Fig 2b), 6CCVD supplies the highest quality SCD material precursors suitable for subsequent top-down fabrication or mechanical exfoliation into high-Q nanocrystals.

The proposed setup (Fig 2a) relies heavily on integrating nanoscale electronic components and controlling surface geometry—areas where 6CCVD excels.

Required Specification6CCVD CapabilityResearch Impact & Value Proposition
Surface Smoothness (NV Depth)Polishing: Ra < 1 nm (SCD)Ensures reliable near-surface NV creation (5-10 nm depth) and minimizes mechanical damping caused by surface defects.
Electrode IntegrationMetalization: Au, Pt, Ti, Pd (Internal Capability)Provides immediate deposition of gate electrodes and microwave antennas directly onto the diamond substrate, accelerating device fabrication.
Scalable ArraysCustom Dimensions: Plates/Wafers up to 125mm (PCD) and custom SCD sizes.Allows researchers to move beyond single-device prototypes toward scalable architectures containing arrays of coupled NV centers.
Custom Thickness/SizeSCD Substrates: 0.1 ”m to 500 ”mEnables optimal material selection, whether for bulk support or thin films required for cantilever/nanocrystal precursors.

6CCVD’s in-house team of PhD material scientists specializes in the growth physics of diamond for quantum technologies. We offer authoritative professional support for:

  • Material Selection: Assisting engineers in selecting the optimal MPCVD diamond grade (SCD, PCD, or BDD) based on specific performance targets (e.g., T2 maximization, thermal management).
  • Integration Optimization: Consultation on maximizing surface quality and choosing appropriate metalization schemes for robust integration with CNTs and cryogenic electronics.
  • Project Extension: Providing technical advice for extending this research into Boron-Doped Diamond (BDD) materials for electrochemistry or superconducting applications derived from the hybrid architecture.

For custom specifications or material consultation, visit 6ccvd.com or contact our engineering team directly.

View Original Abstract

We show that nitrogen-vacancy (NV) centers in diamond interfaced with a suspended carbon nanotube carrying a dc current can facilitate a spin-nanomechanical hybrid device. We demonstrate that strong magnetomechanical interactions between a single NV spin and the vibrational mode of the suspended nanotube can be engineered and dynamically tuned by external control over the system parameters. This spin-nanomechanical setup with strong, intrinsic, and tunable magnetomechanical couplings allows for the construction of hybrid quantum devices with NV centers and carbon-based nanostructures, as well as phonon-mediated quantum information processing with spin qubits.