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Suppressing Spectral Diffusion of Emitted Photons with Optical Pulses

MetadataDetails
Publication Date2016-01-22
JournalPhysical Review Letters
AuthorsHerbert F. Fotso, Adrian Feiguin, D. D. Awschalom, V. V. Dobrovitski
InstitutionsNortheastern University, University of Chicago
Citations31
AnalysisFull AI Review Included

Technical Documentation & Analysis: Suppressing Spectral Diffusion in Solid-State Qubits

Section titled “Technical Documentation & Analysis: Suppressing Spectral Diffusion in Solid-State Qubits”

This document analyzes the research paper “Suppressing Spectral Diffusion of the Emitted Photons with Optical Pulses” (arXiv:1512.05754v1) to highlight the critical role of high-quality diamond materials and connect the experimental requirements directly to 6CCVD’s advanced MPCVD capabilities.


This research demonstrates a robust protocol using optical pulses to stabilize the emission frequency of solid-state qubits, a critical step for scalable quantum networks.

  • Core Problem Addressed: Slow, uncontrollable frequency fluctuations (spectral diffusion) of emitted photons from solid-state qubits (e.g., NV centers in diamond), which severely limits photon indistinguishability and coupling efficiency to photonic cavities.
  • Solution Proposed: A conceptually simple periodic optical pulse sequence (a form of Dynamical Decoupling) applied to the emitter.
  • Key Achievement: The protocol successfully pins the Zero-Phonon Line (ZPL) emission frequency to a desired target frequency ($\omega_0$), effectively suppressing spectral diffusion.
  • Material Requirement: The protocol is demonstrated using parameters relevant to Nitrogen-Vacancy (NV) centers, requiring ultra-high purity, low-strain Single Crystal Diamond (SCD) substrates.
  • Feasibility: Only a few pulses, with realistic parameters (1 ns width, 5-6 ns separation, 0.5 GHz Rabi frequency), are sufficient to suppress diffusion.
  • Impact: The method significantly improves photon indistinguishability, boosting the efficiency of photon-mediated entanglement and quantum interface protocols.

The following hard data points were extracted from the analysis, focusing on the NV center in diamond example:

ParameterValueUnitContext
Emitter SystemNV CenterN/ASolid-state qubit in diamond
Natural ZPL Linewidth ($\Gamma$)$2\pi \cdot 16$MHzCorresponds to $t_0 = 10$ ns spontaneous decay time
Typical Detuning Fluctuation ($\Delta$)$2\pi \cdot 100$MHz$\sim 5\Gamma$ (Fluctuation range)
Control Pulse Width ($t_p$)1nsExperimentally achievable pulse duration
Inter-Pulse Delay ($\tau$)5 - 6nsRequired separation between control pulses
Optical Rabi Frequency ($\Omega$)$0.5$GHzRequired driving strength for 180° rotation
Spectral Weight Shifted to ZPL$\sim 50$%Fraction of emission successfully moved to the target frequency
Rotation Angle Error Tolerance5°Moderate error does not affect control efficiency
Surface Polishing Requirement (Implied)Ra < 1nmNecessary for high-efficiency optical coupling and cavity integration

The experiment relies on advanced theoretical modeling and a specific quantum control sequence applied to the solid-state emitter.

  1. System Definition: The solid-state emitter (qubit) is modeled as a two-level system coupled to a photonic bath. The analysis focuses on the Zero-Phonon Line (ZPL) emission.
  2. Theoretical Framework: The Rotating-Wave Approximation (RWA) is used, simplifying the Hamiltonian by working in a frame rotating at the target frequency ($\omega_0$).
  3. Control Protocol (PDD): A Periodic Dynamical Decoupling (PDD) sequence of short optical control pulses is applied periodically with an inter-pulse delay ($\tau$).
  4. Pulse Function: Each pulse is designed to be a 180° ($\pi$) rotation, which inverts the emitter state ($\sigma_z \rightarrow -\sigma_z$). This reversal cancels the phase accumulation caused by the random detuning ($\Delta$) over the $2\tau$ period.
  5. Analytical Approach: The emission spectrum ($N_\omega$) and correlation functions are calculated using the Markovian approximation and the toggling Heisenberg representation.
  6. Numerical Validation: Results are independently verified using Time-Dependent Density Matrix Renormalization Group (tDMRG) simulations, modeling the photonic bath as a 1-D chain of harmonic oscillators.
  7. Indistinguishability Metric: Photon indistinguishability is quantified by calculating the coincidence count rate for Two-Photon Interference (TPI) experiments, showing significant improvement under pulse control.

The successful implementation of this quantum control protocol, particularly using NV centers, fundamentally relies on the quality and precision of the diamond substrate. 6CCVD provides the necessary materials and engineering services to replicate and advance this research.

Research Requirement6CCVD Material & ServiceTechnical Advantage & Sales Proposition
Ultra-Low Strain & High CoherenceOptical Grade Single Crystal Diamond (SCD): Grown via MPCVD, optimized for ultra-low nitrogen content (high purity) and minimal lattice defects.Critical for Qubit Stability: High-purity SCD minimizes background noise and internal strain, maximizing the coherence time and reducing the intrinsic spectral diffusion of NV centers.
Precise Device IntegrationCustom Dimensions and Thickness: SCD wafers available in thicknesses from 0.1 ”m up to 500 ”m. Custom plates/wafers up to 125 mm (PCD) available for large-scale integration efforts.Scalability and Flexibility: Supports the fabrication of large-area quantum devices and precise integration into complex photonic structures (e.g., solid immersion lenses, waveguides).
High-Efficiency Optical InterfaceUltra-Smooth Polishing: SCD surfaces polished to achieve roughness Ra < 1 nm.Maximized Purcell Enhancement: Essential for minimizing scattering losses and ensuring optimal coupling efficiency between the ZPL emission and external photonic cavities, a key goal of this research.
Integrated Control ElectrodesCustom Metalization Services: In-house deposition of Au, Pt, Pd, Ti, W, and Cu.Enabling Active Control: Allows researchers to integrate microwave or strain electrodes directly onto the diamond surface for fine-tuning the NV center frequency or applying the required optical control pulses.
Advanced Material RequirementsBoron-Doped Diamond (BDD) Capability: Available for projects requiring conductive diamond layers (e.g., for integrated field-effect devices or charge state control).Extending Research Scope: Provides a pathway to explore similar spectral control protocols in other solid-state systems or environments requiring conductive diamond interfaces.

6CCVD’s in-house PhD team specializes in optimizing MPCVD diamond growth parameters for quantum applications. We offer comprehensive engineering support to assist researchers in selecting the ideal material grade, crystallographic orientation, and processing techniques required for quantum network and photon entanglement projects.

For custom specifications or material consultation, visit 6ccvd.com or contact our engineering team directly.

View Original Abstract

In many quantum architectures the solid-state qubits, such as quantum dots or color centers, are interfaced via emitted photons. However, the frequency of photons emitted by solid-state systems exhibits slow uncontrollable fluctuations over time (spectral diffusion), creating a serious problem for implementation of the photon-mediated protocols. Here we show that a sequence of optical pulses applied to the solid-state emitter can stabilize the emission line at the desired frequency. We demonstrate efficiency, robustness, and feasibility of the method analytically and numerically. Taking nitrogen-vacancy center in diamond as an example, we show that only several pulses, with the width of 1 ns, separated by few ns (which is not difficult to achieve) can suppress spectral diffusion. Our method provides a simple and robust way to greatly improve the efficiency of photon-mediated entanglement and/or coupling to photonic cavities for solid-state qubits.