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Long-range photon-mediated gate scheme between nuclear spin qubits in diamond

MetadataDetails
Publication Date2016-01-04
JournalPhysical review. B./Physical review. B
AuthorsAdrian Auer, Guido Burkard
InstitutionsUniversity of Konstanz
Citations11
AnalysisFull AI Review Included

Technical Documentation: Photon-Mediated Quantum Gates in Diamond NV Centers

Section titled “Technical Documentation: Photon-Mediated Quantum Gates in Diamond NV Centers”

6CCVD Analysis of arXiv:1507.08468v1: Long-range photon-mediated gate scheme between nuclear spin qubits in diamond


This research proposes a theoretical framework for implementing a universal controlled-Z (CZ) quantum gate between two distant nitrogen nuclear spin qubits embedded in NV centers within diamond. The scheme leverages virtual cavity photon exchange mediated by external lasers.

  • Ultra-Fast Gate Speed: The predicted gate operation time ($T_{\text{CZ}}$) is below 100 nanoseconds (ns), achieving speeds four orders of magnitude faster than the measured nuclear spin decoherence time ($T_2 \approx 5 \text{ ms}$).
  • Long-Range Coupling: The mechanism enables deterministic coupling between distant NV centers, a fundamental requirement for scalable quantum information processing.
  • Mechanism: The gate relies on nuclear-spin dependent scattering of laser photons into a common optical cavity mode, facilitated by the hyperfine interaction difference ($\delta A$) between the NV ground and excited states.
  • Material Requirement: Successful implementation demands ultra-high quality Single Crystal Diamond (SCD) integrated with high-Q optical cavities.
  • Q-Factor Demand: Achieving fast gate times ($T_{\text{CZ}} \approx 20 \text{ ns}$) requires cavity quality factors ($Q$) in the range of $10^6$ to $10^7$.
  • Isotope Versatility: The scheme is validated for both the intrinsic nitrogen isotopes: ${}^{14}\text{N}$ (Spin I=1) and ${}^{15}\text{N}$ (Spin I=1/2).

The following hard data points are extracted from the analysis, highlighting the critical physical parameters required for the proposed quantum gate.

ParameterValueUnitContext
Predicted Gate Time ($T_{\text{CZ}}$)< 100nsUniversal Controlled-Z (CZ) gate
Required Cavity Q-Factor$10^6$ - $10^7$DimensionlessFor $T_{\text{CZ}} \approx 20 \text{ ns}$ operation
Nuclear Spin Decoherence Time ($T_2$)$\approx 5$msMeasured at room temperature
Magnetic Field (B)120GUsed for theoretical calculations
Electron Gyromagnetic Ratio ($\gamma_{\text{e}}/2\pi$)2.803MHz/GNV electron spin parameter
${}^{14}\text{N}$ Nuclear Spin (I)1DimensionlessQubit candidate
${}^{15}\text{N}$ Nuclear Spin (I)1/2DimensionlessQubit candidate
${}^{14}\text{N}$ Ground State Hyperfine ($A_{\text{gs}}/2\pi$)-2.2MHzLongitudinal coupling
${}^{15}\text{N}$ Excited State Hyperfine ($A_{\text{es}}/2\pi$)61MHzLongitudinal coupling
Laser Rabi Frequency ($\Omega/2\pi$)100 - 400MHzUsed for coupling strength calculations (Fig. 3)
Energy Gap (Ground to Excited State, $E_{\text{g}}$)1.945eVNV orbital transition energy

The theoretical implementation of the long-range CZ gate relies on advanced quantum optics and perturbation theory applied to the NV-cavity system.

  1. System Modeling: The combined system of a single NV center, an optical cavity, and an external laser field is described using a time-dependent Hamiltonian $H(t)$, incorporating electron ($H_{\text{e}}$), nuclear ($H_{\text{n}}$), and hyperfine ($H_{\text{hf}}$) interactions.
  2. Hyperfine Dependence: The analysis leverages the significant difference ($\delta A$) in hyperfine coupling between the NV ground and excited states (excited state coupling is $\approx 20$ times stronger). This difference forms the basis of the nuclear-spin dependent scattering effect.
  3. Schrieffer-Wolff (SW) Transformation (First Pass): A SW transformation is applied to eliminate the intermediate virtual transition to the excited state, resulting in an effective ground-state Hamiltonian $H^{(\text{gs})}$. This step isolates the nuclear-spin dependent scattering process.
  4. Two-Qubit Extension: The model is extended to two distant NV centers (NV 1 and NV 2) coupled to a common cavity mode, each driven by an individual laser.
  5. Schrieffer-Wolff Transformation (Second Pass): A second SW transformation is applied to eliminate the virtual cavity photon mode, decoupling the nuclear spin degree of freedom from the cavity field.
  6. Effective Hamiltonian Derivation: This yields an effective Hamiltonian $H_{\text{eff}}$ containing the two-qubit interaction term $H_{\text{int}} = -g_{12}|11\rangle\langle 11|$, where $g_{12}$ is the effective coupling strength.
  7. Gate Implementation: The universal CZ gate is implemented by setting the interaction time $T_{\text{CZ}} = \pi/g_{12}$.

The realization of this ultra-fast quantum gate scheme requires diamond materials with exceptional purity, precise surface quality, and integrated fabrication capabilities. 6CCVD is uniquely positioned to supply the necessary MPCVD diamond substrates and engineering services.

Research Requirement6CCVD Solution & CapabilityTechnical Advantage for Quantum Applications
Ultra-High Purity Substrates (Essential for long $T_2$ coherence)Optical Grade Single Crystal Diamond (SCD)Provides the lowest native defect density and highest chemical purity, crucial for maximizing the nuclear spin coherence time ($T_2$) well beyond the required 5 ms.
Integrated High-Q Cavities (Requires smooth surfaces, $Q \ge 10^6$)Precision Polishing (Ra < 1 nm for SCD)Ultra-smooth surfaces are mandatory for minimizing optical scattering losses, enabling the fabrication of high-Q photonic crystal cavities in bulk diamond, as referenced in the paper.
Custom Device Geometry (For coupling and strain control)Custom Dimensions and Thickness (SCD up to 500 ”m thick; Plates/wafers up to 125 mm PCD)Allows engineers to specify exact wafer dimensions and thicknesses required for deep etching, focused ion beam (FIB) structuring, and integration into specific optical setups.
Electrical/Magnetic Control (Requires electrodes for B-field and Rabi driving $\Omega$)In-House Custom Metalization (Au, Pt, Pd, Ti, W, Cu)Enables the deposition of high-quality, low-loss metal contacts and micro-wires directly onto the diamond surface for precise control of external magnetic fields and microwave excitation.
Isotopic Control (For ${}^{14}\text{N}$ or ${}^{15}\text{N}$ qubits)Custom Material Doping and GrowthWhile the paper focuses on intrinsic N, 6CCVD can provide substrates with controlled nitrogen incorporation or isotopically enriched diamond (e.g., low ${}^{13}\text{C}$ content) to further extend $T_2$ coherence times.

To replicate or extend this research into a functional device, researchers require:

  • Optical Grade Single Crystal Diamond (SCD): Necessary for hosting isolated, high-coherence NV centers and supporting high-Q optical structures.
  • Custom Thickness SCD: To optimize the coupling efficiency between the NV centers and the integrated photonic cavity mode.

6CCVD offers full customization critical for scaling this quantum architecture:

  • Precision Laser Cutting: For creating specific chip sizes and geometries required for mounting and optical alignment.
  • Multi-Layer Metalization Stacks: We provide complex metal stacks (e.g., Ti/Pt/Au) tailored for robust electrical contacts and superconducting circuits if required for cryogenic operation.
  • Substrate Preparation: We deliver substrates with specified crystallographic orientation and low surface roughness (Ra < 1 nm) essential for subsequent lithography and etching processes used in cavity fabrication.

6CCVD’s in-house team of PhD material scientists and engineers specializes in MPCVD growth parameters optimized for quantum applications. We provide authoritative support for material selection, defect engineering, and surface preparation necessary for NV-based quantum computing and quantum memory projects.

For custom specifications or material consultation, visit 6ccvd.com or contact our engineering team directly.

View Original Abstract

Defect centers in diamond are exceptional solid-state quantum systems that\ncan have exceedingly long electron and nuclear spin coherence times. So far,\nsingle-qubit gates for the nitrogen nuclear spin, a two-qubit gate with a\nnitrogen-vacancy (NV) center electron spin, and entanglement between nearby\nnitrogen nuclear spins have been demonstrated. Here, we develop a scheme to\nimplement a universal two-qubit gate between two distant nitrogen nuclear\nspins. Virtual excitation of an NV center that is embedded in an optical cavity\ncan scatter a laser photon into the cavity mode; we show that this process\ndepends on the nuclear spin state of the nitrogen atom. If two NV centers are\nsimultaneously coupled to a common cavity mode and individually excited,\nvirtual cavity photon exchange can mediate an effective interaction between the\nnuclear spin qubits, conditioned on the spin state of both nuclei, which\nimplements a universal controlled-$\textit{Z}$ gate. We predict operation times\nbelow 100 nanoseconds, which is several orders of magnitude faster than the\ndecoherence time of nuclear spin qubits in diamond.\n